Thermodynamics, Kinetics and Structural Evolution of ε-LiVOPO4 over Multiple Lithium Intercalation

In this work, we demonstrate the stable cycling of more than one Li in solid-state-synthesized {$\epsilon$}-LiVOPO4 over more than 20 cycles for the first time. Using a combination of density functional theory (DFT) calculations, X-ray pair distribution function (PDF) analysis and X-ray Absorption Near Edge Structure (XANES) measurements, we present a comprehensive analysis of the thermodynamics, kinetics and structural evolution of {$\epsilon$}-LixVOPO4 over the entire lithiation range. We identify two intermediate phases at x = 1.5 and 1.75 in the low-voltage regime using DFT calculations, and the computed and electrochemical voltage profiles are in excellent agreement. Operando PDF and EXAFS techniques show a reversible hysteretic change in the short (\textbackslash textless 2 \textbackslash AA) V-O bond lengths coupled with an irreversible extension of the long V-O bond (\textbackslash textgreater 2.4 \textbackslash AA) during low-voltage cycling. Hydrogen intercalation from electrolyte decomposition is a possible explanation for the {$\sim$} 2.4 \textbackslash AA V-O bond and its irreversible extension. Finally, we show that LixVOPO4 is likely a pseudo-1D ionic diffuser with low electronic conductivity using DFT calculations, which suggests that nano-sizing and carbon coating is necessary to achieve good electrochemical performance in this material.